Also in environment...

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Carbon capture technology:
Amine scrubbing
Flue gases pass through an amine solution that traps up to 98 per cent of CO2. The solution must be heated to release the trapped gas, resulting in a loss of generating efficiency of 15-30%. It works well with gas-fired generators, and can be used with coal if contaminants such as sulphur are removed first.


Oxyfuel
Fuel is combusted in concentrated oxygen instead of air. The resulting flue gases contain only water and CO2, which can be separated in a condenser. All components for this process are commercially available, but separating oxygen from air is expensive, resulting in around a 10% loss in generating efficiency.


Physical absorption
CO2 is physically absorbed under high pressure or high temperature onto a high surface area solid, such as zeolite or activated carbon; it is released by lowering the pressure or temperature. This process is already used in the commercial production of hydrogen, but is currently considered unsuitable on a large scale due to low absorption capacity.
Separation with membranes
Polymeric or palladium membranes allow one component in a gas to pass through faster than another, thus separating its components. Most cannot achieve full separation in one stage so require multiple levels, increasing costs. Solvent assisted membranes, combining the best aspects of scrubbing and membranes show great potential, but are not fully developed and still very expensive.


Pre-combustion capture
Natural gas is combusted in an oxygen-poor environment, producing carbon monoxide and hydrogen. The carbon monoxide may then be converted into CO2 in a catalytic reactor and separated from the hydrogen. Steam methane reforming uses high temperature and low pressure to separate the CO2 and hydrogen in the fuel. The resulting hydrogen from both processes can be used in a modified gas turbine generator or fuel cells.


Carbon storage technology:

Saline aquifers

CO2 is injected into a saline aquifer - a layer of porous rock containing salt water beneath the seabed or the land. As it is less dense than water, the CO2 will rise to the top where it is trapped by a non-porous ‘cap rock’. Even if the aquifer connects with the ocean, the gas should remain inside for several thousand years (assuming the cap rock covers hundreds of square kilometres). If the cap rock is dome shaped, the gas will be trapped inside like air trapped within an upturned cup. The long-term effects on the aquifer are uncertain. It is possible that the gas could migrate through unknown faults in the cap rock, or that increased pressure and changes in geochemistry could cause leaks.


Depleted oil and gas reservoirs
Oil and gas reservoirs are also layers of porous rock covered by a cap rock. Many are dome shaped and their integrity is assured, since they have already held high-pressure gases and liquids for millions of years. Thousands of these reservoirs are nearing the end of their productive lives and could store CO2. The cost of exploitation would be small, since most have an established infrastructure. However, after years of drilling, some oil and gas fields often have many wells, each of which would have to be located and sealed before the CO2 is injected.


Salt caverns
Caverns are widely used for the storage of natural gas. The pressure and temperature in such caverns makes it possible that CO2 could be stored in liquid form without the need for surface compressors. The availability and capacity of salt caverns is not great, making for high costs; there is also the potential of leakage if water enters the cavern.


 

A bright future for fossil fuels?

Will storing greenhouse gases in underground reservoirs allow us to tackle climate change immediately, while making an easier transition to a low-carbon economy?

250 km of the coast of Norway, the Sleipner-West gas platform stands over the stormy waters of the North Sea. It looks no different to any of the other huge conglomerations of steel that dot the waters of Norway’s highly productive gas and oil fields, but this platform is home to a unique and controversial experiment. Some believe it will be an essential step towards the rapid and substantial reductions in greenhouse gas emissions necessary to prevent global warming; others see it as a dangerous attempt to dump industrial waste beneath the ocean floor.


Since 1996, Norwegian petroleum company Statoil has been pumping a million tonnes of carbon dioxide (CO2) a year into a saline aquifer 800 metres below the seabed. Rather than escaping into the atmosphere, Statoil scientists believe the gas will remain trapped within the aquifer for thousands of years, thus making no contribution to the greenhouse effect.


The CO2 stored so far only amounts to 3 per cent of Norway’s annual emissions, but its total capacity could be as much as 600 billion tonnes of gas. According to Dr Tore Torp, manager of the project, this means, “the entire carbon dioxide emissions from all the power stations in Europe could be deposited in this structure for 600 years.”


Few dispute that climate change is fact, or that human release of CO2 into the atmosphere is its main cause. With each passing year, more evidence accumulates warning us of the dire consequences we face if we do not address the problem very soon. Yet still the political will to address the problem is lacking.


The Kyoto Accords of 1997 were supposed to be the first step towards tackling climate change, committing the world’s biggest polluters to emissions reductions by 2010. But the intervening years have seen the agreement steadily eroded, and it suffered a critical blow when the Bush administration pulled out in 2001. Even some of Kyoto’s most enthusiastic backers in the EU do not look like meeting their targets. It would be the final nail in the treaty’s coffin if, as recent announcements have hinted, Russia does not ratify.


The politics involved are complicated, but it all seems to come down to one thing in the end - money. A Russian presidential aide stated that Kyoto would place, “significant limitations on the economic growth of Russia.” He was echoing the words of George W Bush, who abandoned the treaty claiming it would damage the US economy. Whether or not these arguments are valid, there is no question that fossil fuels are the foundation of the world economy; doing without them would require dramatic changes in the way our society functions. We citizens of the West are oil and gas junkies, and few of us are willing to suffer the hardship of going ‘cold turkey’.


In this context, Statoil’s project (and others like it) may offer a middle way, giving immediate reductions of greenhouse gas emissions, but allowing a more gradual shift from fossil fuels to renewables. We could effectively put the carbon genie back in its bottle. The big question is - will it work?


The concept of capturing CO2 and storing it underground, a process known as geological carbon sequestration, has been around for at least 25 years. Gas-separation technology is used every day in heavy industry; CO2 is also routinely pumped into oil fields nearing the end of their lives, forcing out the remaining oil in a process known as enhanced oil recovery. However, it is only in the last decade that policy makers began looking seriously into its potential for reducing emissions of greenhouse gases.


CO2 is present in all flue gases produced by burning fossil fuels. However, it only constitutes a small part of the total volume; most of the flue gas is nitrogen, oxygen and water vapour. Before it can be stored, the CO2 must be separated out from the other gases.


Many proven technologies, such as chemical scrubbing, physical absorption or separation with membranes, can achieve this. It is also possible to process a fuel before combustion, separating it into pure hydrogen (which produces only water when combusted) and CO2. These methods can capture up to 80 per cent of the CO2 for each unit of electricity generated, a substantial reduction.


Applications for this technology are not limited to power generation. Major industries like iron and steel production, cement manufacture and oil refining account for three quarters of industrial CO2 emissions, around 60 per cent of which could be captured. Large-scale production of pure hydrogen could also allow a faster shift to zero-emissions vehicles using fuel cell technology. Broad application of carbon capture could put us well on the way to the 60 per cent reduction emissions necessary to stabilise atmospheric concentrations of greenhouse gases and prevent further climate change.


Distributing the captured gas would require little innovation. Existing networks of natural gas pipelines would need only minor modifications. Onshore pipelines already transport CO2 over hundreds of kilometres in the USA. There is also no shortage of suitable geological structures, from salt caverns and saline aquifers to disused oil fields and unminable coal seams. The total storage capacity of these underground reservoirs is many times greater than the projected global CO2 output over the next 50 years.


There are only two carbon sequestration projects in action today. The Sleipner-West project in Norway works by removing excess CO2 from a natural gas field and re-injecting it into a neighbouring aquifer. The Weyburn project in Canada is pumping a million tonnes of the gas per year (delivered via a 320 kilometre pipeline from a synfuels plant in the USA) into a depleted oil well, forcing out an anticipated 122 million extra barrels of oil over its twenty-year duration. Both are crucial test cases, and so far very successful.


The actual cost of implementing carbon sequestration on a commercial scale is more uncertain. Transporting and storing gas is fairly inexpensive; the greatest part of the cost would be capturing the CO2. In an October report, the British Department of Trade and Industry (DTI) concluded that the cost of carbon storage under the North Sea would add 16-36% to the current price per unit of electricity. If used in conjunction with oil recovery, the price would increase by 3-16%, due to the offsetting effect of increased oil productivity. This compares to an estimated price increase of around 25% per unit of electricity to achieve the government’s goal of generating a fifth of our electricity from wind power by 2020.


Offsetting this cost and making carbon sequestration commercially viable would require a strong policy incentive. Statoil’s motivation for pumping CO2 into the Utsira aquifer is the £86,000 per day they would have to pay in Norwegian carbon taxes if they were to release it into the atmosphere. If a similar project is to be implemented in the UK, the DTI says it is vital that the European Union’s Emissions Trading Scheme gives financial credit for the abatement of greenhouse emissions. This would provide the necessary incentive for investors in the technology, but will only be considered if long-term storage is proven safe.


On the night of 22 August 1986, an underwater volcanic explosion in Cameroon’s Lake Nyos released a huge cloud of carbon dioxide over the surrounding countryside. CO2 is an asphyxiant and is heavier than air; it covered the land in a suffocating blanket that extended 15 miles from the lakeshore. 1,700 villagers were killed, 845 were hospitalised and 3000 cattle lay dead in the fields.


This tragic natural disaster shows the full horror that a sudden rupture in an onshore storage reservoir filled with CO2 could entail. The effect of such a release under water is largely unknown, but would likely have equally lethal consequences for sea life. Slow leakage from a reservoir would not have such a dire effect, but would ultimately put the gas back into the atmosphere and make the whole exercise pointless. Clearly, if we put CO2 under the ground, we need to be sure that it will stay there for thousands of years.


Scientists involved with the projects in Norway and Canada are confident of their safety and reliability. Dr Tore Torp, who has been using seismic surveys to study the Sleipner aquifer since 1999, believes the CO2 will remain there for thousands of years. “Once it dissolves in the water,” he says, “it will be very secure. You would have to pump it out.” Similar surveys conducted at the Weyburn site also show that so far the CO2 is staying put. Scientists there are currently developing computer models to determine how the gas will behave over the next 5000 years.


The data in these cases is certainly positive, but the extent to which it can be applied to other sites over the necessary timescales is questionable. Every potential reservoir has a unique geological structure. Each would have to be assessed for safety before a sequestration project could begin - a fact that leaves environmental groups deeply sceptical.


“There is virtually no evidence of what the leakage rate is likely to be,” says Roger Higman, climate change campaigner for Friends of the Earth. “One per cent per year would be absolutely unacceptable. You would lose virtually all of it within 130 years. Even a leakage of 0.1 per cent would produce a greenhouse effect that future generations would be hard pressed to stop. It’s like the issue of nuclear waste management; it’s potentially impossible to prove that something won’t happen over a timescale of a thousand years. The only thing you can guarantee is that if you don’t take the oil, gas or coal out of the well in the first place, you don’t have a problem.” The consensus in the environmental community is concentrating on novel technologies that may never come to fruition is foolish when we already know that approaches like energy efficiency and renewables are effective.


The debate over the future of carbon sequestration is only just beginning, but it seems likely that it will be a part of future energy policy. In an October report, the DTI made it part of their overall strategy to reduce CO2 emissions by 60% before 2050. The outline for a possible demonstration project in the North Sea is expected later this year. The US Department of Energy is particularly keen, with plans to start pumping CO2 into a depleted oil field in Wyoming in 2006, and more projects likely to follow. The Dutch government, and the EU-sponsored ‘CO2Store’ project, are investigating other sites in Europe, including one in the Dulais Valley of South Wales.


Many eyes will be focussed on these projects in the coming years. Whatever the eventual outcome, there can be no question that a problem as serious as climate change needs immediate action, using as broad a spectrum of solutions as possible. “There isn’t one ‘magic bullet’ solution,” says Nick Riley of the British Geological Survey. “We need renewables, energy-saving, carbon dioxide capture and storage – the whole lot. We need to attack this from every available front and we have to do it all over the next few decades.”

 

 

Statoil

CO2 Capture Project

UK Deparment of the Environment - Climate Change

The Pew Centre (USA)

The Tyndall Centre (UK)

CO2 Sequestration

Friends of the Earth

Greenpeace

British Geological Survey

CO2 Store

 

All text and images copyright James Herron 2000-2004. Additional images supplied by free-stock-photos.com and freefoto.com. Email mail@jamesherron.com